TENTATIVE SYLLABUS FOR FIRST SEMESTER ORGANIC CHEMISTRY - HONORS and MAJORS
(Please consult http://www.temple.edu/chem-help for revisions.)

CHEMISTRY 181/191
Fall Semester 2001; MWF 10:40-11:30; BE415

Instructor: D. Dalton , BE340, Telephone 215-204-7138; Facsimile 215-204-1532
e-mail: dalton@temple.edu;URL: http://astro.temple.edu/~dalton
Office Hours: MWF 9:30-10:30 and TuTh 10:30-11:30

TEXTBOOK: John McMurry, "Organic Chemistry", 5th Edition, 1999, Brooks-Cole Publishing Co. is required.


You should read each chapter before it's lecture date given in the syllabus below.


The "Study Guide and Solutions Manual for Organic Chemistry " by Susan McMurry (also from Brooks-Cole Publishing Co.) is recommended. Both are available in the T.U. Bookstore. Any other organic chemistry text is a useful supplement and a variety can be found in Paley Library as well as the Chemistry Department Library . Additionally, there is a considerable amount of "online" help. There is a more-or-less complete textbook called the "Virtual Textbook of Organic Chemistry" by Professor William Reusch at MSU, "Organic Chemistry OnLine" by professor P.R. Young at Illinois, and "WEB-sters' Organic Chemistry" from the Lawrence Livermore Laboratory to name just a few.

Inexpensive sets of molecular models may be purchased in the T.U. Bookstore .


The purpose of this course is to enable you to understand the basic principles of organic chemistry. To succeed you will need to know and use the nomenclature of organic chemistry and you will need to be able to understand structural drawings and draw structures of some simple organic compounds yourself. You will need learn about the dynamics and reactivity of organic molecules and master sufficient spectroscopy to convince yourself that regions outside the visible portion of the spectrum can be utilized to facilitate our understanding of structure as well as what transpires during reactions.

Further it is important to understand:


Some Friendly Advice: Organic Chemistry is a difficult course. For many, it will be the most difficult and time-consuming of your college career. You can make it easier on yourself by doing the following: (1) Do as many problems as you have time for beyond that minimum assigned . (2) Study regularly. If you fall behind, it's hard to catch up. (3) Memorize as much as you can, paying attention to summaries at the end of each chapter. Since there is too much material to memorize everything, you should have enough at your command so that it can be applied to understanding theory and method.

So, to reiterate...experience dictates...

OTHER TOPICS OF INTEREST


RECITATION:

You MUST register for a recitation section of the course. Quizzes will be given in recitation and a portion of your final grade depends upon the scores you receive (see below). It is common to find that questions you did not have time to ask (or for which there was not enough time for a complete answer to be given) in lecture can be discussed in recitation.


LABORATORY:

Chemistry 183 (Majors) and Chemistry 193 (Honors) is a separate course, which has Chemistry 181 or 191 (respectively) as a co-requisite. Information for those Laboratory courses is provided separately when you go to laboratory and questions should be directed to the Organic Chemistry Laboratory Coordinator: Dr. A. Findeisen; BE 400, (215-204-7161), afindeis@astro.temple.edu.

However, it has been a tradition at Temple University to utilize the Honors/Majors laboratory as a "test-bed" for new experiments i.e., those not necessarily found in the Laboratory Text book (currently "Microscale Organic Laboratory" by D.W. Mayo, R.M. Pike, and P.K. Trumper published by John Wiley & Sons, Inc.). Therefore, I am attaching a tentative laboratory schedule at the end of this syllabus which is similar (or identical) to what you will get when you go to laboratory. Changes may be instituted during the term.
SCHEDULING:

Your attendance at all lectures and recitations is expected and regular attendance is positively correlated with success in this course.


EXAMINATIONS and GRADING:

Grading is based upon a percentage scale. If you score more than 85% you are doing "A" work; scores less than 50% generally are unsatisfactory. Borderline grades are decided upon in consultation with recitation teaching assistants (TA's). There will be two 50 minute examinations worth 200 points each (for a total of 400 points) given during regular class time and a final examination worth 400 points (on Friday, 14 December 2001; 8:30-10:30 AM ). The examinations are NOT multiple choice (the operating assumption being that if you know something you can write it down). Old examinations for this course are posted on the "Retrospective" portion of the chem-help site site (http://www.temple.edu/chem-help) but the questions will not be repeated and thus the old examinations should be used to help show what kinds of problems can be expected. The recitation score is 200 points (from 5 quizzes worth 50 points each with the lowest grade omitted).

The maximum score is 1000 points.

There will be NO MAKE-UP QUIZZES IN RECITATION. If you miss an exam for any reason, your grade will be decided upon the work that you have completed.

PLEASE NOTE: Except for the final examination where time constraints preclude my preferences, I grade all of the lecture examinations myself. I believe this helps me understand where lack of communication is leading to difficulties. The grading copy will be posted on the chem-help site (http://www.temple.edu/chem-help) as well as on my site shortly after the examination is given. Graded papers will be returned to you either in your Recitation class or in the Lecture portion of the class as soon as possible.


INCOMPLETES/WITHDRAWAL:

Students may withdraw from the course without penalty (Grade of "W") any time up to and through Monday, 19 November.

The grade "I" (Incomplete) will be given only to students who have amassed 300 points or more. Obtaining the grade "I" also requires a signed form (available from your instructor or academic advisors) indicating the reason for the grade "I" and stating specifically what work remains to be done and by what date the work will be completed. Failure to provide such a form will result in the grade "F" being submitted at the end of the term.


EXAMINATION POLICY:

All quizzes and examinations are "Closed Book". No books, notes, models, computers, or reference material may be consulted during the test period. You will not need a calculator. Giving or receiving information during examinations is a violation of the Temple Student Discipline Code and will result, at minimum, in a grade of "F" for this course.

A grading copy will be posted on this site and on the chem-help (http://www.temple.edu/chem-help) site. I do not currently plan on discussing the examination in lecture or requesting the examination be discussed in recitation unless you have questions .


PROBLEMS

Answers to all assigned problems can be found in the Study Guide /Solutions Manual or the text itself. It is essential that you work through each problem and understand the theory/method used for its solution. It is important to do the work before the recitation in which it is discussed so that questions you have can be answered. Experience has shown that students who do more than the assigned problems do well in this course.


SCHEDULE

Chemistry 181/191 (August - December 2001)

Week beginning:

Topic (Chapter in McMurry)

Problems (in McMurry)

27 August

Chapters 1 (Structure and Bonding) and 2 (Polar Bonds and Their Consequences)

Chapter 1 ; 1, 2 ,4 - 8, 10 -15, 17, 19, 21, 23, 24, 36a,b, 37a, 42, 43

3 September

Chapter 2 (Polar Bonds and Their Consequences)

Chapter 2; 1 - 10, 11, 13, 16 - 19, 21, 24, 25, 26, 27, 33, 35, 48

10 September

Chapter 3 (Alkanes and Cycloalkanes)

Chapter 3; 1 - 5, 8 - 13, 16, 17, 18, 20, 22, 26, 27, 35

17 September

Chapter 4 (Stereochemistry)

Chapter 4;1 - 4, 6, 7, 9 - 15, 17, 21, 32, 35, 39
QUIZ #1 in recitation.

24 September

Chapter 5 (Organic Reaction Overview)

Chapter 5: 1 - 8, 12 - 15, 17, 18, 20, 23, 24, 31, 34, 40

1 October

Chapter 6 (Alkenes)

Chapter 6: 1, 2, 4, 5 - 7, 10, 11, 13, 14 -16, 18 - 20, 24, 25, 27, 37, 39, 46, 47
QUIZ #2 in recitation.
EXAMINATION #1 in lecture. Chapters 1-5 on (tentative) Friday, 5 October

8 October

Chapter 7 (Alkenes)

Chapter 7: 1 - 4, 6 - 10, 12, 13, 15 - 18, 23, 24, 25, 30, 42, 49, 54

15 October

Chapter 8 (Alkynes)

Chapter 8: 1, 2, 3, 5 - 9, 11, 12, 13, 22, 23, 28, 30, 36, 37

22 October

Chapter 9 (Stereochemistry)

Chapter 9: 1 - 11, 14, 17 - 20, 23, 27, 35, 40, 41, 47, 52

29 October

Chapter 10 (Alkyl Halides)

Chapter 10: 1 - 6, 9 - 14, 18, 31, 33, 35, 41
QUIZ #3 in recitation.
EXAMINATION #2 in lecture. Chapters 5-9 (tentative) Friday, 2 November.

5 November

Chapter 11 (Elimination and Nucleophilic Substitution)

Chapter 11: 1 - 7, 9, 12, 15, 16, 29, 33, 39, 40, 47, 48, 52, 62

12 November

Chapter 12 (Mass Spectrometry and IR Spectroscopy)

Chapter 12: 1 - 4, 7 - 13, 16 - 23, 36, 38, 46

19 November0

Chapter 13 (NMR)

Chapter 13; 3 - 20, 22, 27, 28, 32 - 49

26 November

Chapter 14 (Dienes and UV)

Chapter 14: 1 - 6, 9 - 13, 15, 16, 27, 28, 31, 33, 41 QUIZ #4 in recitation.

3 December

Chapter 15 (Aromaticity)

Chapter 15; 1-3, 5-8, 11, 12, 20, 22a,c, 25, 27, 29, 37, 44a,b
. Review.

December 6, 2001 is a study day. Final examinations begin on Monday 10 December. The final examination for this course is scheduled for Friday, 14 December 2001; 8:30-10:30 AM.