TENTATIVE SYLLABUS FOR SECOND SEMESTER HONORS AND MAJORS ORGANIC CHEMISTRY
(Please consult http://photon.chem.temple.edu for revisions from any campus computer.)

CHEMISTRY 2922 (HONORS) and CHEMISTRY 2212 (MAJORS)
Spring Semester 2010
Lecture: MWF 10:00-10:50; BE415
Recitation: F 1:00-1:50; BE415

Instructor: D. Dalton , BE340, Telephone 215-204-7138; Facsimile 215-204-1532
e-mail: david.dalton@temple.edu; URL: http://astro.temple.edu/~dalton
Office Hours: MWF 11:00 AM - 12:30 PM and other times by appointment

TEXTBOOK:Jones, Maitland "Organic Chemistry", 3rd Edition, 2005, W.W.Norton & Company is required.


You should read each chapter before the lecture for which it is scheduled.
Any other organic chemistry text book is a useful supplement and a variety can be found in Paley Library or in the Science, Engineering, Architecture Library (SEAL) in the School of Engineering. Additionally, there is a considerable amount of "online" help. There is a more-or-less complete textbook called the "Virtual Textbook of Organic Chemistry" by Professor William Reusch at MSU, "WEB-sters' Organic Chemistry" from the Lawrence Livermore Laboratory and the Chapman & Hall ChemnetBase , available through the Temple Library and the Thieme Chemistry, Science of Synthesis (Houben-Weyl Methoden) from the same source, to name just a few.

Inexpensive sets of molecular models may be purchased in the T.U. Bookstore .


The purpose of the two semester course in Organic Chemistry is to enable you to understand the basic principles of the subject. The material in the second term builds upon what you learned in the first term.To succeed you will need to remember and use the nomenclature of organic chemistry and you will need to be able to understand structural drawings and draw structures of more complex organic compounds. You will continue to learn about the dynamics and reactivity of organic molecules now expanded to aromatic systems and the vast subject of carbonyl chemistry. Your mastery of spectroscopy (IR, UV and NMR) will be expanded upon to facilitate your understanding of structure as well as what transpires during reactions.

Further it is important to understand:


The second term in Organic Chemistry builds upon the first. It is not less time-consuming . Having succeeded in the first term you probably know that you should :

OTHER TOPICS OF INTEREST


RECITATION:

You MUST register for a Recitation Section of the course. Quizzes will be given in recitation and a portion of your final grade depends upon the scores you receive (see below). It is common to find that questions you did not have time to ask (or for which there was not enough time for a complete answer to be given) in lecture can be discussed in recitation.


LABORATORY:

Chemistries 2214 (Majors) and 2924 (Honors) are separate courses. Those courses have Chemistries 2213 (Majors) and 2923 (Honors) as prerequisites. The Honors and Majors meet together to the extent possible. Information for the Laboratory courses is provided separately when you go to laboratory and questions should be directed to the Organic Chemistry Laboratory Coordinator: Dr. A. Findeisen; BE 400, (215-204-7161), afindeis@temple.edu and to your Laboratory Instructor.

However, because you will be taking that course and for your convenience, I am attaching a tentative laboratory schedule at the end of this syllabus which is similar (or identical) to what you will get when you go to laboratory. Changes may be instituted before the term begins (in which case this will have been replaced) and changes may also occur during the term.
SCHEDULING:

Your attendance at all lectures and recitations is expected and regular attendance is positively correlated with success in this course.


EXAMINATIONS and GRADING:

Grading is based upon a percentage scale. If you score more than 85% you are doing "A" work; scores less than 50% generally are unsatisfactory. Borderline grades are decided upon in consultation with recitation teaching assistants (TA's). There will be two 50 minute examinations worth 200 points each (for a total of 400 points) given during regular class time or recitation and a final examination worth 400 points. Tthe examinations are NOT multiple choice (the operating assumption being that if you know something you can write it down). Old examinations for this course are posted on the "Retrospective" portion of the http://photon.chem.temple.edu site that can be accessed from any ON CAMPUS computer but the questions will not be repeated and thus the old examinations should be used to help show what kinds of problems can be expected. The recitation score is 200 points (from 4 quizzes worth 50 points each. The lowest grade will be omitted and 50 points assigned on the basis of class participation).

The maximum score is 1000 points.

There will be NO MAKE-UP QUIZZES IN RECITATION. If you miss an exam for any reason, your grade will be decided upon the work that you have completed.

PLEASE NOTE: Except for the final examination where time constraints may preclude my preferences, I grade all of the lecture examinations myself. I believe this helps me understand where lack of communication is leading to difficulties.


NOTICE. A PORTION OF THE FINAL EXAMINATION IN THIS COURSE WILL CONSIST OF THE STANDARDIZED AMERICAN CHEMICAL SOCIETY MULTIPLE CHOICE TEST SO THAT YOU MAY COMPARE YOUR UNDERSTANDING WITH OTHERS ACROSS THE NATION

Disability Impact Statement: Any student who has a need for accommodation based on the impact of a disability should contact me privately to discuss the specific situation as soon as possible. (S)he should also contact Disability Resources and Services at 215-204-1280 in Room 100 Ritter Annex so that we can attempt to coordinate reasonable accommodations for her/his documented disabilities.


Drop/Add: During the first week of classes students may rearrange their schedules without special approval from the instructor as long as the desired section(s) are open. Students should check the Diamond Line (215-204-2525) phone registration system frequently or Temple's On-line Course Schedule . Both systems will allow students to determine which sections are currently open. Note that a section that was closed in the early morning may have opened up by the afternoon, so check frequently.


Withdrawal: Students may withdraw from the course without penalty (Grade of "W") any time up to and through Monday, 1 February. After that grace period the "W" grade is only given in accordance with institutional procedure. The procedure to obtain a "W" grade after 12 September is governed by the Temple University Policy (#03.12.12) on Withdrawal. Please click here to view the policy.


Incomplete: Please note that an Incomplete ("I") Grade is only given in accord with institutional procedures. The "I" grade cannot be given until the specific requirements have been met and forms filled out, signed and submitted. This course is governed by the Temple University Policy (#03.12.13) on Incompletes. Please click here to view the policy.


EXAMINATION POLICY:

All quizzes and examinations are "Closed Book". No books, notes, models, computers, or reference material may be consulted during the test period. You will not need a calculator. Giving or receiving information during examinations is a violation of the Temple Student Discipline Code and will result, at minimum, in a grade of "F" for this course.

A grading copy will be posted on the http://photon.chem.temple.edu site (that can be accessed from any ON CAMPUS computer) shortly after the examination is given. Graded papers will be returned to you either in your Recitation class or in the Lecture portion of the class as soon as possible.

I do not currently plan on discussing the examination in lecture or requesting the examination be discussed in recitation unless you have questions .


PROBLEMS

Answers to all assigned problems can be found in the Study Guide /Solutions Manual (on reserve in the Science, Engineering, Architecture Library -SEAL) or the text itself. It is essential that you work through each problem and understand the theory/method used for its solution. It is important to do the work before the recitation in which it is discussed so that questions you have can be answered. Experience has shown that students who do more than the assigned problems do well in this course.


SCHEDULE

Chemistry 2212 and 2923 (January - May 2010)

Week beginning:

Topic (Chapter in Jones)

Problems (in Jones)

18 January

Chapter 13 (Conjugation and Aromaticity)

Chapter 13; 13.1-13.4, 13.9, 13.13, 13.17, 13.21, 13.27

25 January

Chapter 14 (Aromatic Compounds - (Substitution)

Chapter 14; 14.1, 14.5-14.9, 14.10, 14.15-14.21, 14.21, 14.27, 14.28, 14.32, 14.41-14.43, 14.52, 14.53, 14.66

1 Feburary

Chapters 14 & 15 (Spectroscopy) Last day to drop class

(Trinity Software) and Chapter 15: 15.1, 15.3, 15.6, 15.7, 15.10, 15.12, 15.16, 15.17, 15.23-15.26

8 February

Chapters 15 & 16 (Carbonyl Reactions 1)

Chapter 16: 16.5, 16.7, 16.8, 16.10-16.16, 16.18, 16.20. 16.21, 16.24, 16.37, 16.39, 16.60
QUIZ #1 (Chapters 1-15) in recitation.

15 February

Chapters 16 & 17 (Carbonyl Reactions II)

Chapter 17: 17.1-17.5, 17.9, 17.9, 17.13, 17.14, 17.18, 17.19, 17.24,17.28-17.31, 17.50,17.61-17.63 EXAMINATION #1 in recitation. Chapters 1-16 on (tentative) Friday, 19 February

22 February

Chapter 17 (Carbonyl Reactions II)

Chapter 17 (Table 17.1): 17.1-17.5, 17.9, 17.9, 17.13, 17.14, 17.18, 17.19, 17.24,17.28-17.31, 17.50,17.61-17.63

1 March

Chapter 17 &18 (Intoduction to carboxylate chemistry)

Chapter 18 (Table 18.1): 18.1-18.3, 18.9, 18.10, 18.16, 18.20, 18.21, 18.40, 18.41
QUIZ #2 (Chapters 1-17) in recitation.

15 March

Chapter 18 (Carboxylic Acids)

Chapter 18 (Table 18.1): 18.1-18.3, 18.9, 18.10, 18.16, 18.20, 18.21, 18.40, 18.41

22 March

Chapter 19 (Acyl compounds)

Chapter 19: 19.4. 19.5-19.12, 19.17, 19.18, 19.23, 19.26, 19.30, 19.31, 19.34, 19.35, 19.36. 19.76
QUIZ #3 (Chapters 1-18) in recitation.

29 March

Chapters 19 & 20 (Orbital Symmetry)

Chapter 19: 19.4. 19.5-19.12, 19.17, 19.18, 19.23, 19.26, 19.30, 19.31, 19.34, 19.35, 19.36. 19.76 Last day to withdraw.

5 April

Chapter 20 (Orbital Symmetry)

Chapter 20: 20.1-20.5, 20.14, 20.17, 20.20. 20.21 (Rules pp1165-1166)
EXAMINATION #2 in recitation. Chapters 1-20 (tentative) Friday, 9 April

12 April

Chapter 21 (Intramolecular Reactions)

Chapter 21: 21.1, 21.5, 21.7, 21.16, 21.23, 21.37

19 April

Chapters 22 & 23 (Carbohydrates and Amino Acids)

QUIZ #4 in recitation. (Chapter 1-22), Friday, 23 April)

26 April

Chapter 23 (Amino Acids and Nucleic Acids)

Review

Tuesday 4 May and Wednesday 5 May are study days. Final examinations begin on Thursday, 6 May. The final examination for this course is scheduled for Friday, 7 May from 10:30 AM - 12:30 PM.