TENTATIVE SYLLABUS FOR FIRST SEMESTER HONORS ORGANIC CHEMISTRY
(Please consult http://photon.chem.temple.edu for revisions from any campus computer.)

CHEMISTRY 2921
Fall Semester 2008
Lecture: MWF 10:40-11:30; BE323 (tentative)
Recitation: F 1:40-2:30; BE323 (tentative)

Instructor: D. Dalton , BE340, Telephone 215-204-7138; Facsimile 215-204-1532
e-mail: david.dalton@temple.edu; URL: http://astro.temple.edu/~dalton
Office Hours: MWF 11:30 AM - 12:30 PM and other times by appointment

TEXTBOOK:Jones, Maitland "Organic Chemistry", 3rd Edition, 2005, W.W.Norton & Company is required.


You should read each chapter before the lecture for which it is scheduled.
Any other organic chemistry text book is a useful supplement and a variety can be found in Paley Library or in the Science, Engineering, Architecture Library (SEAL) in the School of Engineering. Additionally, there is a considerable amount of "online" help. There is a more-or-less complete textbook called the "Virtual Textbook of Organic Chemistry" by Professor William Reusch at MSU, "WEB-sters' Organic Chemistry" from the Lawrence Livermore Laboratory and the Chapman & Hall ChemnetBase , available through the Temple Library and the Thieme Chemistry, Science of Synthesis (Houben-Weyl Methoden) from the same source, to name just a few.

Inexpensive sets of molecular models may be purchased in the T.U. Bookstore .


The purpose of this course is to enable you to understand the basic principles of organic chemistry. To succeed you will need to know and use the nomenclature of organic chemistry and you will need to be able to understand structural drawings and draw structures of some simple organic compounds yourself. You will need learn about the dynamics and reactivity of organic molecules and master sufficient spectroscopy to convince yourself that regions outside the visible portion of the spectrum can be utilized to facilitate our understanding of structure as well as what transpires during reactions.

Further it is important to understand:


Some Friendly Advice: Organic Chemistry is a difficult course. For many, it will be the most difficult and time-consuming of your college career. You can make it easier on yourself by doing the following: (1) Do as many problems as you have time for beyond that minimum assigned . (2) Study regularly. If you fall behind, it's hard to catch up. (3) Memorize as much as you can, paying attention to summaries at the end of each chapter. Since there is too much material to memorize everything, you should have enough so it can be applied to understanding theory and method.

So, to reiterate...experience dictates...

OTHER TOPICS OF INTEREST


RECITATION:

You MUST register for a recitation section of the course. Quizzes will be given in recitation and a portion of your final grade depends upon the scores you receive (see below). It is common to find that questions you did not have time to ask (or for which there was not enough time for a complete answer to be given) in lecture can be discussed in recitation.


LABORATORY:

Chemistry 193 is a separate course that has Chemistry 191 as a co-requisite. Information for the Laboratory course is provided separately when you go to laboratory and questions should be directed to the Organic Chemistry Laboratory Coordinator: Dr. A. Findeisen; BE 400, (215-204-7161), afindeis@temple.edu and to your laboratory instructor.

However, because you will be taking that course and for your convenience, I am attaching a tentative laboratory schedule at the end of this syllabus which is similar (or identical) to what you will get when you go to laboratory. Changes may be instituted before the term begins (in which case this will have been replaced) and changes may also occur during the term.
SCHEDULING:

Your attendance at all lectures and recitations is expected and regular attendance is positively correlated with success in this course.


EXAMINATIONS and GRADING:

Grading is based upon a percentage scale. If you score more than 85% you are doing "A" work; scores less than 50% generally are unsatisfactory. Borderline grades are decided upon in consultation with recitation teaching assistants (TA's). There will be two 50 minute examinations worth 200 points each (for a total of 400 points) given during regular class time or recitation and a final examination worth 400 points (on Friday, 16 December 2005; 8:30-10:30 AM ). The examinations are NOT multiple choice (the operating assumption being that if you know something you can write it down). Old examinations for this course are posted on the "Retrospective" portion of the http://photon.chem.temple.edu site that can be accessed from any ON CAMPUS computer but the questions will not be repeated and thus the old examinations should be used to help show what kinds of problems can be expected. The recitation score is 200 points (from 4 quizzes worth 50 points each. The lowest grade will be omitted and 50 points assigned on the basis of class participation).

The maximum score is 1000 points.

There will be NO MAKE-UP QUIZZES IN RECITATION. If you miss an exam for any reason, your grade will be decided upon the work that you have completed.

PLEASE NOTE: Except for the final examination where time constraints preclude my preferences, I grade all of the lecture examinations myself. I believe this helps me understand where lack of communication is leading to difficulties.


Disability Impact Statement: Any student who has a need for accommodation based on the impact of a disability should contact me privately to discuss the specific situation as soon as possible. (S)he should also contact Disability Resources and Services at 215-204-1280 in Room 100 Ritter Annex so that we can attempt to coordinate reasonable accommodations for her/his documented disabilities.


Drop/Add: During the first week of classes students may rearrange their schedules without special approval from the instructor as long as the desired section(s) are open. Students should check the Diamond Line (215-204-2525) phone registration system frequently or Temple's On-line Course Schedule . Both systems will allow students to determine which sections are currently open. Note that a section that was closed in the early morning may have opened up by the afternoon, so check frequently.


Withdrawal: Students may withdraw from the course without penalty (Grade of "W") any time up to and through Monday, 12 September. After that grace period the "W" grade is only given in accordance with institutional procedure. The procedure to obtain a "W" grade after 12 September is governed by the Temple University Policy (#03.12.12) on Withdrawal. Please click here to view the policy.


Incomplete: Please note that an Incomplete ("I") Grade is only given in accord with institutional procedures. The "I" grade cannot be given until the specific requirements have been met and forms filled out, signed and submitted. This course is governed by the Temple University Policy (#03.12.13) on Incompletes. Please click here to view the policy.


EXAMINATION POLICY:

All quizzes and examinations are "Closed Book". No books, notes, models, computers, or reference material may be consulted during the test period. You will not need a calculator. Giving or receiving information during examinations is a violation of the Temple Student Discipline Code and will result, at minimum, in a grade of "F" for this course.

A grading copy will be posted on the http://photon.chem.temple.edu site (that can be accessed from any ON CAMPUS computer) shortly after the examination is given. Graded papers will be returned to you either in your Recitation class or in the Lecture portion of the class as soon as possible.

I do not currently plan on discussing the examination in lecture or requesting the examination be discussed in recitation unless you have questions .


PROBLEMS

Answers to all assigned problems can be found in the Study Guide /Solutions Manual or the text itself. It is essential that you work through each problem and understand the theory/method used for its solution. It is important to do the work before the recitation in which it is discussed so that questions you have can be answered. Experience has shown that students who do more than the assigned problems do well in this course.


SCHEDULE

Chemistry 2921 (September - December 2008)

Week beginning:

Topic (Chapter in Jones)

Problems (in Jones)

1 Sept

Chapters 1 (Orbitals) and 2 (Alkanes)

Chapter 1; 1.8, 1.12, 1.13, 1.19, 1.20, 1.24. 1.29 1.36 1.45, 1.50, 1.52-1.55

8 September

Chapters 2 (Alkanes) and 3 (Alkenes and Alkynes)

Chapter 2; 2.4, 2.7, 2.10, 2.12, 2.14, 2.15, 2.17, 2.20, 2.23, 2.24, 2.31-2.37

15 September

Last day to drop.

Chapter 3 (Alkenes and Alkynes)

Chapter 3; 3.3, 3.5-3.8, 3.15, 3.16, 3.19, 3.21, 3.26, 3.27+3.28, 3.30, 3.33, 3.44, 3.48. Last day to drop class.

22 September

Chapter 4 (Stereochemistry) and Chapter 15 (Analytical Chemistry: Spectroscopy)

Chapter 4; 4.1, 4.2, 4.5, 4.12,4.17-4.19, 4.23, 4.27, 4.37 4.51
QUIZ #1 (Chapters 1-3) in recitation.

29 September

Chapter 4 (Stereochemistry) and Chapter 15 (Analytical Chemistry: Spectroscopy)

Chapter 15; 15.1, 15.3, 15.6, 15.7, 15.12(*), 15.16, 15.17, 15.23(*)-15.26(*) (* = solved) NB This chapter will be revisited for the problems at its end... EXAMINATION #1 in recitation. Chapters 1-4 on (tentative) Friday, 3 October

6 October

Chapter 5 (Rings) (Use Spartan & WebMo)

Chapter 5; 5.1-5.4, 5.11, 5.15, 5.17, 5.19, 5.26-5.28, 5.45

13 October

Chapter 6 (Alkyl Halides, etc.)

Chapter 6; 6.4, 6.6, 6.7-6.9(*), 6.14, 6.15, 6.28
QUIZ #2 (Chapters 1-5 & 15) in recitation.

20 October

Chapter 7 (Substitution and Elimination)

Chapter 7; 7.2, 7.6, 7.8, 7.11, 7.12, 7.15, 7.18, 7.19, 7.22, 7.27, 7.28, 7.35-7.38, 7,46, 7.58, 7.74

27 October

Chapter 7 (Substitution and Elimination) and Chapter 8 (Equilibria)

Chapter 8; 8.3, 8.9, 8.13, 8.21
QUIZ #3 (Chapters 1-7 & 15) in recitation.

3 November

Last day to withdraw.

Chapter 9 (Additions to Alkenes 1)

Chapter 9; 9.2 (*), 9.6, 9.11, 9.13, 9.14-9.16, 9.21, 9.22, 9.26, 9.38, 9.49, 9.54

10 November

Chapter 10 (Additions to Alkenes 2 and Alkynes too)

Chapter 10; 10.2, 10.4, 10.7, 10.11, 10.12, 10.14, 10.19, 10.20, 10.21, 10.32, 10.43, 10.55
EXAMINATION #2 in recitation. Chapters 1-9 & 15 (tentative) Friday, 14 November

17 November

Chapter 11 (Radical Reactions) and Chapter 12 (Dienes)

Chapter 11; 11.4, 11.11, 11.12, 11.19, 11.22, 11.23, 11.41, 11.46

24 November

Chapter 12 (Dienes)

Chapter 12; 12.4, 12.5, 12.8, 12.13, 12.14, 12.19, 12.27. 12.41 QUIZ #4 in recitation. (Chapter 1-11 & 15, Wednesday, 26 November)

1 December

Chapter 13 (Conjugation and Aromaticity)

Chapter 13; 13.1-13.4, 13.9, 13.13, 13.17, 13.21, 13.27

8 December

Review

Thursday 11 December and Friday 12 December are study days. Final examinations begin on Monday, 15 December. The final examination for this course is scheduled for Friday, 19 December 2008 from 9:00 - 11:00 AM.