TENTATIVE SYLLABUS FOR FIRST SEMESTER ORGANIC CHEMISTRY
(Please consult http://www.temple.edu/chem-help for revisions.)

CHEMISTRY 121, SECTION 001
Spring Semester 1999; MWF 10:40-11:30; BE166

Instructor: D. Dalton , BE340, Telephone 215-204-7138; Facsimile 215-204-1532
e-mail: dalton@sgi.chem.temple.edu; dalton@astro.ocis.temple.edu;
Office Hours: MWF 9:30-10:30 and 11:30-12:30

NOTICE: WE ARE USING OCOL written by P. R. Young. (http://http://gopher.chem.uic.edu/organic/organic.html)

and Web-sters Organic Chemistry (http://ep.llnl.gov:80/msds/orgchem/)

The purpose of this course is to enable you to understand the basic principles of organic chemistry. To succeed you will need to know and use the nomenclature of organic chemistry and you will need to be able to understand structural drawings and draw structures of some simple organic compounds yourself. You will need learn about the dynamics and reactivity of organic molecules and master sufficient spectroscopy to convince yourself that regions outside the visible portion of the spectrum can be utilized to facilitate our understanding of structure as well as what transpires during reactions.

Further it is important to understand:


TEXT: The required text for this course is Maitland Jones, Jr., "Organic Chemistry", W. W. Norton, Co., N. Y. 1997. Recommended problems for your study from Maitland Jones, Jr., "Organic Chemistry" are provided later in this syllabus. You should read each chapter before it is lectured upon. The "Organic Chemistry Study Guide/Solutions Manual" by Jones and Gingrich is also available to help you. Both are to be found in the T.U. Bookstore. Inexpensive sets of molecular models may be purchased (Undergraduate Temple University Chemical Society or T.U. Bookstore)


In addition to the textbook ( Maitland Jones, Jr., "Organic Chemistry") it is hoped you will possess the discipline to look at the TOPICS of the scheduled lectures, and then to find (see below) and to read the corresponding material and do problems from elsewhere. To help you in this effort you can rely on:

The ONLINE information can be found HERE (http://astro.temple.edu/~dalton) and at at http://www.temple.edu/chem-help, the Chemistry Department's Help site as well as through two major websites:


OTHER TOPICS OF INTEREST


RECITATION:

You MUST register for a recitation section of the course. Quizzes will be given in recitation and a portion of your final grade depends upon the scores you receive (see below). It is common to find that questions you did not have time to ask (or for which there was not enough time for a complete answer to be given) in lecture can be discussed in recitation.


LABORATORY:

Chemistry 123 (or 183 or 193) is a separate course, which has Chemistry 121 as a co- or pre-requisite. That information is provided separately and questions should be directed to the Lab. Coordinator: Dr. A. Findeisen; BE 400.


SCHEDULING:

Your attendance at all lectures and recitations is expected and regular attendance is positively correlated with success in this course. Although the notes for these Sections are posted on the WEB, you should be aware that using them is NOT a substitute for classroom participation.


GRADING:

Grading is based upon a percentage scale. If you score more than 85% you are doing "A" work; scores less than 50% generally are unsatisfactory. Borderline grades are decided upon in consultation with recitation teaching assistants (TA's). There will be two 50 minute examinations worth 200 points each (for a total of 400 points) given during regular class time and a final examination worth 400 points (on Friday, 7 May 1999; 8:30-10:30 AM ). The examinations are NOT multiple choice (the operating assumption being that if you know something you can write it down). Old examinations for this course are posted on the Chemistry Department's Help site (http://www.temple.edu/chem-help) but the questions will not be repeated and thus the old examinations should be used to help show what kinds of problems can be expected. The recitation score is 200 points (from 5 quizzes worth 50 points each with the lowest grade omitted).

The maximum score is 1000 points.

There will be NO MAKE-UP QUIZZES IN RECITATION. If you miss an exam for any reason, your grade will be decided upon the work that you have completed.

PLEASE NOTE: Except for the final examination where time constraints preclude my preferences, I grade all of the lecture examinations myself. I believe this helps me understand where lack of communication is leading to difficulties. The grading copy will be posted on the Chemistry Department's Help site (http://www.temple.edu/chem-help) shortly after the examination is given. Graded papers will be returned to you either in your Recitation class or in the lecture portion of the class as soon as possible.


INCOMPLETES/WITHDRAWAL:

Students may withdraw from the course without penalty (Grade of "W") any time up to Monday, 19 April.

The grade "I" (Incomplete) will be given only to students who have amassed 300 points or more. Obtaining the grade "I" also requires a signed form (available from your instructor or academic advisors) indicating the reason for the grade "I" and stating specifically what work remains to be done and by what date the work will be completed. Failure to provide such a form will result in the grade "F" being submitted at the end of the term.


EXAMINATION POLICY:

All quizzes and examinations are "Closed Book". No books, notes, models, computers, or reference material may be consulted during the test period. You will not need a calculator. Giving or receiving information during examinations is a violation of the Temple Student Discipline Code and will result, at minimum, in a grade of "F" for this course.

A grading copy will be posted on this site and on the Chemistry Department's Help (http://www.temple.edu/chem-help) site. I do not currently plan on discussing the examination in lecture or requesting the examination be discussed in recitation unless you have questions .


PROBLEMS

Answers to all assigned problems can be found in the Study Guide /Solutions Manual or the text itself. It is essential that you work through each problem and understand the theory/method used for its solution. It is important to do the work before the recitation in which it is discussed so that questions you have can be answered. Experience has shown that students who do more than the assigned problems do well in this course.


SCHEDULE

Chemistry 121 (January - May 1999)

Week beginning:

Topic (Chapter in Jones)

Problems (in Jones)

18 January

Chapters 1 (Atoms, Atomic Orbitals,and Bonding) and 2 (Molecules, Molecular Orbitals, and Bonding)

Chapter 1 questions and Alchemy III software.

25 January

Chapter 3 (Alkanes)

Chapter 1;1,3ad,4ab,5bf,6fg,8ch,9,10,13,14,15ac,16cde

1 February

Chapter 4 (Alkenes and Alkynes)

Chapter 2; 2-5,8 15,17

8 February

Chapter 5 (Stereochemistry)

Chapter 3;1,7,8,11,13,14(any),15-20,21,22,24,25,33
QUIZ #1 in recitation.

15 February

Chapter 6 (Rings)

Chapter 4; 3-7, 9,10,12,13,15,16,20-22,25,30a,31a

22 February

Chapter 7 (Substitution and Elimination Reactions: The SN2, SN1, E2, and E1 Reactions)

Chapter 5; 1-4,7,10-14,16,17,19,20,21,22,24,25,33
QUIZ #2 in recitation.
EXAMINATION #1 in lecture. Chapters 1-5 on (tentative) Friday, 26 February

1 March

Chapter 7 (Substitution and Elimination Reactions: The SN2, SN1, E2, and E1 Reactions)

Chapter 6; 3-8, 10-15, 17,19,21, 30,32,37af, 40

15 March

Chapter 8 (Equilibria)

Chapter 7; 1-5, 7-19, 223, 29, 31

22 March

Chapter 9 (Additions to Alkenes 1)

Chapter 8; 2-8, 10, 11, 12-14, 17a, 18,21

29 March

Chapter 10 (Additions to Alkenes 2; Additions to Alkynes)

Chapter 9; 1,2,6-9, 11,14,16-20, 23,24,26
QUIZ #3 in recitation.
EXAMINATION #2 in lecture. Chapters 5-9 (tentative) Wednesday, 31 March.

5 April

Chapter 11 Radical Reactions)

Chapter 10; 2-4,7-11,12,14,19,20,24,25,27,29,31,32,40,46

12 April

Chapter 12 (Dienes and the Allyl System; 2p Orbitals in Conjugation)

Chapter 11; 3-5,7,9,12,14,16-19,24,26,28

19 April

Chapter 15 (Analytical Chemistry)[Chromatography, MS, IR, NMR]

Chapter 12;1,4,6,9,11,16-21,24,25,27,29,33,40,42,44,47abc,49,54c

26 April

Chapter 15 (Analytical Chemistry)[Chromatography, MS, IR, NMR]

Chapter 15; 2,3,6-9,11,12,16-18,20,21,23-26,34,36,37,43,44,47,
51,54,57,60; QUIZ #4 in recitation.

3 May

Chapter 15 (Analytical Chemistry)[Chromatography, MS, IR, NMR]

Chapter 15; 2,3,6-9,11,12,16-18,20,21,23-26,34,36,37,43,44,47,
51,54,57,60. Review.

The final examination is scheduled for Friday, 7 May 1999; 8:30-10:30 AM.

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